RhodiuM nitrate liquid
Rhodium(III) nitrate
CAS: 10139-58-9
Molecular Formula: N3O9Rh
RhodiuM nitrate liquid - Names and Identifiers
| Name | Rhodium(III) nitrate |
| Synonyms | Rhodiumnitrate rhodium trinitrate Rhodium(III) nitrate RhodiuM nitrate soluti RhodiuM nitrate liquid rhodium(3+) trinitrate RhodiuM(Ⅲ) nitrate solution Rhodium(III) nitrate hydrate Rhodium ICP standard solution Fluka Rhodium internal ICP-MS Standard Fluka Rhodium (III) nitrate solution in nitric acid |
| CAS | 10139-58-9 |
| EINECS | 233-397-6 |
| InChI | InChI=1/3NO3.Rh/c3*2-1(3)4;/q3*-1;+3 |
| InChIKey | VXNYVYJABGOSBX-UHFFFAOYSA-N |
RhodiuM nitrate liquid - Physico-chemical Properties
| Molecular Formula | N3O9Rh |
| Molar Mass | 288.92 |
| Density | 1.41g/mLat 25°C |
| Boling Point | 100 °C |
| Water Solubility | Soluble in alcohol, water, acetone |
| Vapor Presure | 49.8mmHg at 25°C |
| Appearance | Solution |
| Color | Dark orange-brown to red-brown solution |
| Exposure Limit | ACGIH: TWA 0.01 mg/m3NIOSH: IDLH 2 mg/m3; TWA 0.001 mg/m3 |
| Storage Condition | 0-6°C |
| Physical and Chemical Properties | Appearance and properties: amber liquid density: 1.41g/mL at 25°C Boiling Point: 100°C storage conditions: The warehouse is ventilated and dried at low temperature, light weight and light unloading, separate storage from organic matter, reducing agent, sulfur and phosphorus combustible material vapor pressure: 49.8mmHg at 25°C solubility: soluble in water, insoluble in ethanol. |
RhodiuM nitrate liquid - Risk and Safety
| Risk Codes | R8 - Contact with combustible material may cause fire R34 - Causes burns R35 - Causes severe burns R36/38 - Irritating to eyes and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S36 - Wear suitable protective clothing. S23 - Do not breathe vapour. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S17 - Keep away from combustible material. S15 - Keep away from heat. |
| UN IDs | UN 3085 5.1/PG 3 |
| WGK Germany | 3 |
| RTECS | VI9316000 |
| FLUKA BRAND F CODES | 3-10 |
| TSCA | Yes |
| HS Code | 28439090 |
| Hazard Class | 5.1 |
| Packing Group | II |
RhodiuM nitrate liquid - Reference Information
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Overview | The Rhodium nitrate solution is prepared by the interaction of Rhodium and nitric acid, reaction with a base to form a lemon-yellow precipitate Rhodium dioxide pentahydrate. Is a red or yellow deliquescent crystal. As a kind of important catalyst precursor in industrial production, it is widely used in industry. It is also commonly used as an oxidizing agent. |
| quality specification | Rhodium (Rh) content: ≥ 35.0% iron (Fe) content: ≤ 0.001% total metal impurities: ≤ 0.005% |
| Process | The solution is obtained by dissolving rhodium (III) pentahydrate in nitric acid and evaporating the solution on a water bath. |
| Primary use | 1. Noble metal catalyst 2. Oxidant 3. For the preparation of thermocouples |
| safety information | symbol: GHS03 GHS05 signal term: Hazard hazard statement: H272; h314 warning statement: P220; P280; P305 P351 P338; P310 package grade: II hazard Category: 5.1 Transport Code of dangerous goods: UN 3085 5.1/PG 3 WGK Germany:3 hazard category code: R35 Safety Note: S26-S45-S36-S23-S36/39-s17-s15 RTECS No: VI9316000 dangerous goods mark: C |
| Main references | [1] Liu Wen, Li Yong, Zhu Wushun, etc. Determination of rhodium content in rhodium nitrate products by hydrogen reduction gravimetric method [J]. Metallurgical analysis, 2014, 34(8):11-15. [2]http://baike.baidu.com/link? url=qaPotsA3Za9IocO790WB7oGEZCyIDgYA9vE1vpvZtAnArqtQ2smAxh3vvz79Bswv3Q20avQxh0sv84EEyy1GZjqnC3mGhPE1tN2IUq5hOuTc6Y02xezBNxMzDn8FjNPU |
| Use | is used as the oxidant. |
| category | oxidant |
| toxicity grade | poisoning |
| Acute toxicity | Reference range: oral-mouse LD50: 4417 mg/kg; Intraperitoneal mouse LD50: 226 mg/kg |
| explosive hazard characteristics | mixed with reductant, sulfur, phosphorus, etc, friction can burst |
| flammability hazard characteristics | is combustible in combination with organic matter, reducing agent, combustible sulfur and phosphorus; toxic NOx smoke from combustion |
| storage and transportation characteristics | The warehouse is ventilated and dried at low temperature; Light loading and light unloading; With organic matter, reducing agent, sulfur, separate storage of phosphorus flammability |
| fire extinguishing agent | water and sand mist |
Last Update：2024-04-10 22:29:15
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View History
RhodiuM nitrate liquid
S7432sodium
六氟硅酸钾 (METALS BASIS)
GUM DAMMAR
柯利黴素
Terbium(III) carbonate hydrate
Nickel formate
773883-32-2
130892-40-9
116757-66-5
S7432sodium
六氟硅酸钾 (METALS BASIS)
GUM DAMMAR
柯利黴素
Terbium(III) carbonate hydrate
Nickel formate
773883-32-2
130892-40-9
116757-66-5